Raiyn
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Which is academic in a guitar circuit where it will never produce 5V let alone 50.Technically it's all to do with the breakdown of the dielectric, the insulating material, between the two capacitor "plates".
At some given voltage those will break down or short. The technical details are way beyond me, but in simplistic terms, I guess the better the dielectric, the smaller the cap can be for any given voltage.

Allegedly. There hasn't been a blind test yet where anyone could tell the difference. Some of my favorites will throw in a cap of a different value - that literally everyone will pick up on and claim it's the expensive magic cap. The rest they'll guess at with the fervor of a failing math student with a scantron test.Differences in the dielectric and plate size will also give tiny, nuanced, differences in frequency response,